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Supermaterials Repel Space Dangers
By Leonard David
Senior Space Writer
posted: 07:00 am ET
08 December 2000

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HAMPTON, Va. -- A spacecraft takes a hole-making hit from a meteoroid and repairs itself. Huge but super-thin solar sails en route to Alpha Centauri are imbedded with rip-stopping carbon nanotubes. Human waste is used as a death-defying way to shield Mars-bound astronauts against lethal blasts of radiation.

Experts here at NASA's Langley Research Center point to the physical fact: It's a material world after all. These scientists are developing new, experimental materials that in the future could help protect astronauts and spacecraft from the harsh, often unpredictable world of deep space.


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Long Duration Exposure Facility (LDEF) carried various materials to study effects of the space environment. Click to enlarge.
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NASA's Langley Research Center

Scientists believe that the development of new super-light materials could allow for the practical use of solar sails. In theory, a spaceship should be able to propel itself using nothing but the pressure of light, which consists of particles called photons.

"Most people take materials for granted," said Sheila Thibeault, a Langley senior materials research engineer. "If you are a contractor who builds houses, you go to the lumberyard. A seamstress making a dress goes to the fabric store," she said. But these new supermaterials being developed for space are simply improved polymers that are used in common items, like clothing and upholstery.

Punishing environments

Materials launched into space face a spate of dangers. They can be attacked by atomic oxygen in low Earth orbit. Then there's the ultraviolet radiation that degrades them. Spacecraft materials are also sitting ducks for heavy doses of radiation and the passing pings of micrometeoroids and space debris.

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"The properties of a material come from chemical structure. We see how we can make a material more robust for whatever task. Making materials work in extreme temperatures and the other harsh factors of space is critical," Thibeault told SPACE.com.

The testing of space-rated materials on Earth has its drawbacks.

Materials can be subjected in ground chambers to such things as vacuum, radiation and radical temperature swings. "But we don't have a facility that you can simulate everything at once. So we have to put things into space," Thibeault said.

Attack of the atomic oxygen

Langley has long had an interest in how materials react to the space environment.

Carbon nanotubes and buckyballs may be the building material for future spacecraft.

The NASA center developed and managed the Long Duration Exposure Facility (LDEF) program. LDEF was the first experiment-carrying spacecraft that was flown in space, retrieved and then returned to Earth.

The school bus-sized spacecraft was loaded with trays of experiments, exposing scads of materials to the environs of space. LDEF was dropped off in Earth orbit by a space shuttle in April 1984.

Shuttle-snagged in January 1990 and brought home for analysis, LDEF had circled Earth for more than five and a half years. It yielded a bonanza of data on how various materials stand-up to space exposure.

"One big surprise to a lot of people was how hazardous atomic oxygen turned out to be in low Earth orbit," Thibeault said.

The problem stems from reactive oxygen atoms attaching themselves to and attacking carbon atoms in a polymer, which weakens the material.

"It's like a cavity in a tooth. It starts out as a pit, then gets bigger as it wears away the tooth's surface. Then you end up with a cavity," she said.

New polymeric materials, Thibeault said, are now being developed at Langley that are far more resistant to the erosive effects of atomic oxygen.

Suitcase science

Thibeault and her colleagues are currently hard at work on the Materials International Space Station Experiment (MISSE).

Spacewalking astronauts next year are to mount two suitcase-sized experiments on the International Space Station. Each will open to expose a myriad of test patches of items including films, composites, adhesives, coatings and paints. The MISSE suitcases are to ride on the outside of the complex for a year, then will be returned to Earth.

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The hoard of materials include those that are atomic-oxygen resistant, as well as samples that will weather a beating from ultraviolet radiation, or that can survive doses of other radiation types.

Another two MISSE suitcases are to piggyback on the station during a later mission and will battle the effects of space weather for three years.

Mounted at different spots on the orbiting outpost, the MISSE packages are expected to bear a wealth of data useful for future spacecraft designers, Thibeault said.

Rest in peace: rip off

Langley is looking at how huge solar sails can be unfurled in space and made rigid. These sails are intended to harness solar energy to power future spacecraft. Because solar sails need to be so thin, work is centered on making them more durable. So one idea is to impregnate solar sail material with "rip-stop," Thibeault said.

"You can imagine such a thin sail developing a hole, tear or rip. It can propagate out and that would be a disaster. So we're looking at ways to stop a rip," the Langley engineer said.

Nanometer-sized nanotubes imbedded in polymers would not only add strength to the sail, but also provide a rip-stop feature, Thibeault said.

Sealing the deal

Other research at this NASA center is focused on several types of self-healing materials. One tactic is making a material that is impact resistant. If a meteoroid or piece of debris hits the material, the resulting hole will seal itself.

"The heat from the shock wave of the impacting object causes the material to essentially melt...and it melts back into itself," Thibeault said.

The materials scientists at Langley have a vision to produce multifunctional materials. Not only do they have to be tough, they must be lightweight as well. And these miracle materials would do everything: from retarding nasty bouts with atomic oxygen and the Sun's rays, thwart dangerous doses of radiation and defy object impacts.

"Somehow we've got to put all this together and come up with materials that can perform more than one function," Thibeault said.

Waste not…

Thibeault said interplanetary voyages, like future missions to Mars, are fraught with challenges. One tough task is fabricating radiation shielding for astronauts.

Lead-lined spacecraft walls are not the ideal solution, she said. For one, that would be far too heavy.

"We're looking at water and food the astronauts will eat, and the garbage and waste products they'll produce. All that has to be taken into account. And all that can be used as radiation shielding," she said.

Furthermore, as the water is consumed, and food is eaten, the resulting reservoir of both urine and solid waste may prove perfect in replenishing the shielding material, Thibeault said.

"I know it's not very poetic. But you do have this input-output kind of thing."


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