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Microscopic Nanotubes Could Make Ships Lightweight, Superstrong

By Erik Baard
Special to SPACE.com
posted: 07:00 am ET
06 February 2002

nanotube_concepts_020206

Nanotechnology has held a special place in the hearts of science fiction writers for decades. On the printed page and flickering screen, nanites and nanobots have swarmed through the human body, assembled themselves into great towers, and formed clouds in orbit of alien worlds. Indeed, NASA's nanotubes team at the Johnson Space Center in Houston foresees the stuff playing a critical role in nearly every aspect of a ship - from speeding electronics to delivering drugs inside astronauts. But some of the first applications of the new technology of synthesizing carbon nanotubes may be as prosaic as building stronger and lighter wall panels for manned spacecraft and casings for automated probes.

Granted, we're talking phenomenally stronger and lighter. Carbon has long been known to make lightweight, tough materials - you see it every day in diamonds and graphite. But diamonds are brittle tetrahedron crystals and graphite sheets fray. Microscopic tubes of carbon have been spotted in laboratories for years - they look like the coiled shavings of chocolate one might see on a cake. These are called multiwalled nanotubes. Dr. Sumio Ijima of Japan's NEC Corp. officially discovered multiwalled nanotubes in 1991, though carbon "whiskers" had been observed as far back as the 1960s.
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But what has engineers and scientists excited is the single walled kind - carbon nanotubes that are cigar-shaped molecules with atoms connected in a kind of hexagonal chicken wire, with the seams sealed along the vertical axis and in their rounded ends. Such a carbon nanotube, which is now the standard reference when using the term, is wholly self-contained, so it has no reactive edges from which it might unravel. It's also flexible, with great tensile strength. The number most often quoted is, 100-times stronger than steel, at about one-sixth the weight.

"Individual tubes are the strongest, meanest damned thing going," Dr. Richard Smalley of Rice University told SPACE.com. Smalley shared in the 1996 Nobel Prize in chemistry for the 1985 discovery of spheres of 60 carbon atoms, called Buckminster Fullerines or Buckyballs, for the mathematician and architect who invented the geodesic dome structures that the molecules resemble, and aptly enough, who last taught at the Carbondale of Southern Illinois University.

Theoretically, one could create nanotubes that extend from the Earth into space - there's no physical limit to their length. They are currently made using four basic approaches, with two fastest out of the gate: pulsed laser vaporization and electric arc discharge. In the former technique, pulsed lasers strike a catalyst of graphite and metal - cobalt and nickel - which are vaporized into a tube filled with pressurized argon in an oven heated to 1473 degrees Kelvin. In those extreme conditions the nanotubes self-assemble from the carbon vapor and then condense on the flow tube's walls. In the latter, faster, method developed at the University of Montpellier in France, the carbon is also vaporized. But instead, this time catalysts of nickel and yttrium are vaporized from an anode when it's hit with 100 amps of electricity at 35 volts. The nanotubes self assemble in a stainless steel chamber filled with low-pressure helium gas, cooled by water. A newer third method simply decomposes carbon-containing molecules on nanometer-sized particles of metal catalysts.

Smalley's team recently began producing nanotubes from, essentially, car exhaust. High-pressure carbon monoxide (HiPco) is reacted with iron pentacarbonyl, which is also under high pressure, and heated. The iron clusters phase into a gas and the carbon atoms grow into nanotubes around those clusters. A NASA research paper described this method promising because it's rapid and relatively clean, meaning that there's less carbon soot and catalyst to remove to purify samples. Smalley said he could even imagine making huge sheets of carbon that have rounded corners and seamlessly connected sides, a flattened Fullerine just two atoms thick, almost like a giant pita bread. "I'm not sure what you could do with it, but it sure would be cool stuff," Smalley said, but then added that it might be layered and adhered in a superstrong composite.

With promising techniques for real production of the nanotubes in place, it didn't take long for visions of space elevators and skyhook tethers to pop into the minds of dreamy sci-fi writers and hard-nosed aerospace engineers alike. But that's a ways off. Our longest single wall nanotube to date is a millimeter, and even Smalley's technique yields just 10 grams of useful material per day. Even when, in perhaps a decade or so, we start mass-producing carbon nanotubes, they'll be short strands. More likely we'll see small nanotube strands clinging into longer strands through the Van der Waal Force, the same intermolecular attraction that tangles spaghetti or holds the cellulose fibers of hemp rope together.

"In regards to the space elevator using carbon nanotubes - I myself do not personally see the benefit of using single walled or multiwalled carbon nanotubes when composite materials made from graphitic fibers can perform similarly, and much more cheaply.  The bulk use of carbon nanotubes is still a very long way off, and a tremendous amount of development effort will be required for this vision to ever be realized. I think this application for CNTs is a little crazy, but hey, a lot of crazy ideas have eventually found their niche.  It just may take a very long time," argues Dr. Alan M. Cassell, Senior Research Scientist of the Eloret Corporation at NASA Ames Research Center.

As Smalley remarked, "until strong, continuous tubes are in the hands of engineers, it's all idle speculation."

Next page: Uses for nanotubes

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